Mixed er-NHC/phosphine Pd() complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions
A series of novel (NHC)PdCl 2 -PR 3 complexes were synthesized and fully characterized by 1 H, 13 C, 31 P NMR and FT-IR spectroscopy. These complexes showed high catalytic activity toward solvent-free Buchwald-Hartwig amination. Both primary and secondary amines were efficiently utilized under the s...
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Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2019-03, Vol.48 (1), p.3447-3452 |
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Sprache: | eng |
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