Mixed er-NHC/phosphine Pd() complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions
A series of novel (NHC)PdCl 2 -PR 3 complexes were synthesized and fully characterized by 1 H, 13 C, 31 P NMR and FT-IR spectroscopy. These complexes showed high catalytic activity toward solvent-free Buchwald-Hartwig amination. Both primary and secondary amines were efficiently utilized under the s...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2019-03, Vol.48 (1), p.3447-3452 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
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| creator | Ageshina, Alexandra A Sterligov, Grigorii K Rzhevskiy, Sergey A Topchiy, Maxim A Chesnokov, Gleb A Gribanov, Pavel S Melnikova, Elizaveta K Nechaev, Mikhail S Asachenko, Andrey F Bermeshev, Maxim V |
| description | A series of novel (NHC)PdCl
2
-PR
3
complexes were synthesized and fully characterized by
1
H,
13
C,
31
P NMR and FT-IR spectroscopy. These complexes showed high catalytic activity toward solvent-free Buchwald-Hartwig amination. Both primary and secondary amines were efficiently utilized under the same reaction conditions. The solvent-free synthesis of valuable
N
-aryl carbazoles and similar N-heterocyclic systems was described.
A single catalyst for solvent-free Buchwald-Hartwig amination with both primary and secondary amines. |
| doi_str_mv | 10.1039/c9dt00216b |
| format | Article |
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2
-PR
3
complexes were synthesized and fully characterized by
1
H,
13
C,
31
P NMR and FT-IR spectroscopy. These complexes showed high catalytic activity toward solvent-free Buchwald-Hartwig amination. Both primary and secondary amines were efficiently utilized under the same reaction conditions. The solvent-free synthesis of valuable
N
-aryl carbazoles and similar N-heterocyclic systems was described.
A single catalyst for solvent-free Buchwald-Hartwig amination with both primary and secondary amines.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c9dt00216b</identifier><identifier>PMID: 30793148</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Amines ; Aromatic compounds ; Carbazoles ; Carbon 13 ; Catalysis ; Catalytic activity ; Chemical synthesis ; Crystallography ; Fourier transforms ; Infrared spectroscopy ; NMR ; Nuclear magnetic resonance ; Solvents ; Spectrum analysis ; X-ray diffraction</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2019-03, Vol.48 (1), p.3447-3452</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-de94ee9c7c49642ea663ed629192a31ed59f3e5c3836f6d63526be2d856cf4693</citedby><cites>FETCH-LOGICAL-c337t-de94ee9c7c49642ea663ed629192a31ed59f3e5c3836f6d63526be2d856cf4693</cites><orcidid>0000-0003-3333-4384 ; 0000-0002-6604-7034 ; 0000-0003-4732-9949 ; 0000-0002-4822-2484 ; 0000-0003-3820-5442 ; 0000-0001-5313-5812 ; 0000-0001-8941-4856 ; 0000-0001-8638-9261</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30793148$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ageshina, Alexandra A</creatorcontrib><creatorcontrib>Sterligov, Grigorii K</creatorcontrib><creatorcontrib>Rzhevskiy, Sergey A</creatorcontrib><creatorcontrib>Topchiy, Maxim A</creatorcontrib><creatorcontrib>Chesnokov, Gleb A</creatorcontrib><creatorcontrib>Gribanov, Pavel S</creatorcontrib><creatorcontrib>Melnikova, Elizaveta K</creatorcontrib><creatorcontrib>Nechaev, Mikhail S</creatorcontrib><creatorcontrib>Asachenko, Andrey F</creatorcontrib><creatorcontrib>Bermeshev, Maxim V</creatorcontrib><title>Mixed er-NHC/phosphine Pd() complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>A series of novel (NHC)PdCl
2
-PR
3
complexes were synthesized and fully characterized by
1
H,
13
C,
31
P NMR and FT-IR spectroscopy. These complexes showed high catalytic activity toward solvent-free Buchwald-Hartwig amination. Both primary and secondary amines were efficiently utilized under the same reaction conditions. The solvent-free synthesis of valuable
N
-aryl carbazoles and similar N-heterocyclic systems was described.
A single catalyst for solvent-free Buchwald-Hartwig amination with both primary and secondary amines.</description><subject>Amines</subject><subject>Aromatic compounds</subject><subject>Carbazoles</subject><subject>Carbon 13</subject><subject>Catalysis</subject><subject>Catalytic activity</subject><subject>Chemical synthesis</subject><subject>Crystallography</subject><subject>Fourier transforms</subject><subject>Infrared spectroscopy</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Solvents</subject><subject>Spectrum analysis</subject><subject>X-ray diffraction</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpd0c1PwyAYBnBiNDo_Lt41JF7UpFqgpePo5sdM_DrouWHw1rF0tAKd7uh_but0Jp4geX68Ie-D0D6Jz0jMxLkSOsQxJXy8hnokybJIUJasr-6Ub6Ft76etoXFKN9EWizPBSNLvoc978wEag4seRsPzelL5emIs4Cd9fIJVNatL-ACPpdU4TMA4rGSQ5SIYhaUKZm7CAhvbZXjQqMm7LHU0ki68m1fsoCOVxY3V4LCvyjnYEBUOoB1ttelCv4s2Cll62Ps5d9DL9dXzcBTdPd7cDi_uIsVYFiINIgEQKlOJ4AkFyTkDzakggkpGQKeiYJAq1me84JqzlPIxUN1PuSoSLtgOOl7OrV311oAP-cx4BWUpLVSNzynpp2n3LGnp0T86rRpn2991ql0dzRht1elSKVd576DIa2dm0i1yEuddMflQXD5_FzNo8eHPyGY8A72iv0204GAJnFer9K9Z9gXWHJLu</recordid><startdate>20190314</startdate><enddate>20190314</enddate><creator>Ageshina, Alexandra A</creator><creator>Sterligov, Grigorii K</creator><creator>Rzhevskiy, Sergey A</creator><creator>Topchiy, Maxim A</creator><creator>Chesnokov, Gleb A</creator><creator>Gribanov, Pavel S</creator><creator>Melnikova, Elizaveta K</creator><creator>Nechaev, Mikhail S</creator><creator>Asachenko, Andrey F</creator><creator>Bermeshev, Maxim V</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-3333-4384</orcidid><orcidid>https://orcid.org/0000-0002-6604-7034</orcidid><orcidid>https://orcid.org/0000-0003-4732-9949</orcidid><orcidid>https://orcid.org/0000-0002-4822-2484</orcidid><orcidid>https://orcid.org/0000-0003-3820-5442</orcidid><orcidid>https://orcid.org/0000-0001-5313-5812</orcidid><orcidid>https://orcid.org/0000-0001-8941-4856</orcidid><orcidid>https://orcid.org/0000-0001-8638-9261</orcidid></search><sort><creationdate>20190314</creationdate><title>Mixed er-NHC/phosphine Pd() complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions</title><author>Ageshina, Alexandra A ; Sterligov, Grigorii K ; Rzhevskiy, Sergey A ; Topchiy, Maxim A ; Chesnokov, Gleb A ; Gribanov, Pavel S ; Melnikova, Elizaveta K ; Nechaev, Mikhail S ; Asachenko, Andrey F ; Bermeshev, Maxim V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-de94ee9c7c49642ea663ed629192a31ed59f3e5c3836f6d63526be2d856cf4693</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Amines</topic><topic>Aromatic compounds</topic><topic>Carbazoles</topic><topic>Carbon 13</topic><topic>Catalysis</topic><topic>Catalytic activity</topic><topic>Chemical synthesis</topic><topic>Crystallography</topic><topic>Fourier transforms</topic><topic>Infrared spectroscopy</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Solvents</topic><topic>Spectrum analysis</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ageshina, Alexandra A</creatorcontrib><creatorcontrib>Sterligov, Grigorii K</creatorcontrib><creatorcontrib>Rzhevskiy, Sergey A</creatorcontrib><creatorcontrib>Topchiy, Maxim A</creatorcontrib><creatorcontrib>Chesnokov, Gleb A</creatorcontrib><creatorcontrib>Gribanov, Pavel S</creatorcontrib><creatorcontrib>Melnikova, Elizaveta K</creatorcontrib><creatorcontrib>Nechaev, Mikhail S</creatorcontrib><creatorcontrib>Asachenko, Andrey F</creatorcontrib><creatorcontrib>Bermeshev, Maxim V</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ageshina, Alexandra A</au><au>Sterligov, Grigorii K</au><au>Rzhevskiy, Sergey A</au><au>Topchiy, Maxim A</au><au>Chesnokov, Gleb A</au><au>Gribanov, Pavel S</au><au>Melnikova, Elizaveta K</au><au>Nechaev, Mikhail S</au><au>Asachenko, Andrey F</au><au>Bermeshev, Maxim V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mixed er-NHC/phosphine Pd() complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2019-03-14</date><risdate>2019</risdate><volume>48</volume><issue>1</issue><spage>3447</spage><epage>3452</epage><pages>3447-3452</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>A series of novel (NHC)PdCl
2
-PR
3
complexes were synthesized and fully characterized by
1
H,
13
C,
31
P NMR and FT-IR spectroscopy. These complexes showed high catalytic activity toward solvent-free Buchwald-Hartwig amination. Both primary and secondary amines were efficiently utilized under the same reaction conditions. The solvent-free synthesis of valuable
N
-aryl carbazoles and similar N-heterocyclic systems was described.
A single catalyst for solvent-free Buchwald-Hartwig amination with both primary and secondary amines.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>30793148</pmid><doi>10.1039/c9dt00216b</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-3333-4384</orcidid><orcidid>https://orcid.org/0000-0002-6604-7034</orcidid><orcidid>https://orcid.org/0000-0003-4732-9949</orcidid><orcidid>https://orcid.org/0000-0002-4822-2484</orcidid><orcidid>https://orcid.org/0000-0003-3820-5442</orcidid><orcidid>https://orcid.org/0000-0001-5313-5812</orcidid><orcidid>https://orcid.org/0000-0001-8941-4856</orcidid><orcidid>https://orcid.org/0000-0001-8638-9261</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2019-03, Vol.48 (1), p.3447-3452 |
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| language | eng |
| recordid | cdi_pubmed_primary_30793148 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Amines Aromatic compounds Carbazoles Carbon 13 Catalysis Catalytic activity Chemical synthesis Crystallography Fourier transforms Infrared spectroscopy NMR Nuclear magnetic resonance Solvents Spectrum analysis X-ray diffraction |
| title | Mixed er-NHC/phosphine Pd() complexes and their catalytic activity in the Buchwald-Hartwig reaction under solvent-free conditions |
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