Bond Shortening (1.4 Å) in the Singlet and Triplet Excited States of [Ir2(dimen)4]2+ in Solution Determined by Time-Resolved X-ray Scattering

Ground- and excited-state structures of the bimetallic, ligand-bridged compound Ir2(dimen)4 2+ are investigated in acetonitrile by means of time-resolved X-ray scattering. Following excitation by 2 ps laser pulses at 390 nm, analysis of difference scattering patterns obtained at eight different time...

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Veröffentlicht in:Inorganic chemistry 2011-10, Vol.50 (19), p.9329-9336
Hauptverfasser: Haldrup, Kristoffer, Harlang, Tobias, Christensen, Morten, Dohn, Asmus, van Driel, Tim Brandt, Kjær, Kasper Skov, Harrit, Niels, Vibenholt, Johan, Guerin, Laurent, Wulff, Michael, Nielsen, Martin Meedom
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Sprache:eng
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