Adducts of triangular silver() 3,5-bis(trifluoromethyl)pyrazolate with thiophene derivatives: a weak interaction model of desulfurization
-Acidic triangular silver( i ) 3,5-bis(trifluoromethyl)pyrazolate ( Ag 3 pz 3 ) can form 1:1 adducts with dibenzothiophene (DBT), 4,6-dimethyldibenzothiophene (DMDBT), benzothiophene (BT), and 2,5-dimethylthiophene (DMT), which are stabilized by weak AgS and AgC contacts and sometimes by stacking an...
Gespeichert in:
Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2019-11, Vol.48 (43), p.16162-16166 |
---|---|
Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | -Acidic triangular silver(
i
) 3,5-bis(trifluoromethyl)pyrazolate (
Ag
3
pz
3
) can form 1:1 adducts with dibenzothiophene (DBT), 4,6-dimethyldibenzothiophene (DMDBT), benzothiophene (BT), and 2,5-dimethylthiophene (DMT), which are stabilized by weak AgS and AgC contacts and sometimes by stacking and, therefore, may represent a weak interaction model for some adsorptive desulfurization processes.
Triangular silver(
i
) 3,5-bis(trifluoromethyl)pyrazolate (
Ag
3
pz
3
) can quickly sequester dibenzothiophene (DBT) in isooctane, forming insoluble 1:1 adduct and thus possessing potential use in desulfurization technology. |
---|---|
ISSN: | 1477-9226 1477-9234 |
DOI: | 10.1039/c9dt03344k |