Adducts of triangular silver() 3,5-bis(trifluoromethyl)pyrazolate with thiophene derivatives: a weak interaction model of desulfurization
-Acidic triangular silver( i ) 3,5-bis(trifluoromethyl)pyrazolate ( Ag 3 pz 3 ) can form 1:1 adducts with dibenzothiophene (DBT), 4,6-dimethyldibenzothiophene (DMDBT), benzothiophene (BT), and 2,5-dimethylthiophene (DMT), which are stabilized by weak AgS and AgC contacts and sometimes by stacking an...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2019-11, Vol.48 (43), p.16162-16166 |
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| container_issue | 43 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 48 |
| creator | Liu, Rongrong Zhang, Wenhua Wei, Donghui Chen, Jing-Huo Ng, Seik Weng Yang, Guang |
| description | -Acidic triangular silver(
i
) 3,5-bis(trifluoromethyl)pyrazolate (
Ag
3
pz
3
) can form 1:1 adducts with dibenzothiophene (DBT), 4,6-dimethyldibenzothiophene (DMDBT), benzothiophene (BT), and 2,5-dimethylthiophene (DMT), which are stabilized by weak AgS and AgC contacts and sometimes by stacking and, therefore, may represent a weak interaction model for some adsorptive desulfurization processes.
Triangular silver(
i
) 3,5-bis(trifluoromethyl)pyrazolate (
Ag
3
pz
3
) can quickly sequester dibenzothiophene (DBT) in isooctane, forming insoluble 1:1 adduct and thus possessing potential use in desulfurization technology. |
| doi_str_mv | 10.1039/c9dt03344k |
| format | Article |
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i
) 3,5-bis(trifluoromethyl)pyrazolate (
Ag
3
pz
3
) can form 1:1 adducts with dibenzothiophene (DBT), 4,6-dimethyldibenzothiophene (DMDBT), benzothiophene (BT), and 2,5-dimethylthiophene (DMT), which are stabilized by weak AgS and AgC contacts and sometimes by stacking and, therefore, may represent a weak interaction model for some adsorptive desulfurization processes.
Triangular silver(
i
) 3,5-bis(trifluoromethyl)pyrazolate (
Ag
3
pz
3
) can quickly sequester dibenzothiophene (DBT) in isooctane, forming insoluble 1:1 adduct and thus possessing potential use in desulfurization technology.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c9dt03344k</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Adducts ; Adsorptivity ; Benzothiophene ; Crystallography ; Desulfurizing ; Dibenzothiophene ; Interaction models ; NMR ; Nuclear magnetic resonance ; Silver</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2019-11, Vol.48 (43), p.16162-16166</ispartof><rights>Copyright Royal Society of Chemistry 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c314t-14a56abe42778610f90c097528014ba268d75ca363408f4ecfa3a8bab42a6d653</citedby><cites>FETCH-LOGICAL-c314t-14a56abe42778610f90c097528014ba268d75ca363408f4ecfa3a8bab42a6d653</cites><orcidid>0000-0003-2820-282X ; 0000-0002-9766-6188 ; 0000-0002-1379-0684</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Liu, Rongrong</creatorcontrib><creatorcontrib>Zhang, Wenhua</creatorcontrib><creatorcontrib>Wei, Donghui</creatorcontrib><creatorcontrib>Chen, Jing-Huo</creatorcontrib><creatorcontrib>Ng, Seik Weng</creatorcontrib><creatorcontrib>Yang, Guang</creatorcontrib><title>Adducts of triangular silver() 3,5-bis(trifluoromethyl)pyrazolate with thiophene derivatives: a weak interaction model of desulfurization</title><title>Dalton transactions : an international journal of inorganic chemistry</title><description>-Acidic triangular silver(
i
) 3,5-bis(trifluoromethyl)pyrazolate (
Ag
3
pz
3
) can form 1:1 adducts with dibenzothiophene (DBT), 4,6-dimethyldibenzothiophene (DMDBT), benzothiophene (BT), and 2,5-dimethylthiophene (DMT), which are stabilized by weak AgS and AgC contacts and sometimes by stacking and, therefore, may represent a weak interaction model for some adsorptive desulfurization processes.
Triangular silver(
i
) 3,5-bis(trifluoromethyl)pyrazolate (
Ag
3
pz
3
) can quickly sequester dibenzothiophene (DBT) in isooctane, forming insoluble 1:1 adduct and thus possessing potential use in desulfurization technology.</description><subject>Adducts</subject><subject>Adsorptivity</subject><subject>Benzothiophene</subject><subject>Crystallography</subject><subject>Desulfurizing</subject><subject>Dibenzothiophene</subject><subject>Interaction models</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Silver</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpd0U1PGzEQBuBVRaUC7aV3JEtcQsWCv_bDvUVpoRWRuKTn1ax3ljhx1sH2Jgr_gH_NpkEgcZqR5tHMSG-SfGf0ilGhrrVqIhVCyuWn5JjJokgVF_Loref5l-QkhAWlnNOMHyfP46bpdQzEtSR6A91Db8GTYOwG_eiCiMssrU0YDbPW9s67Fcb5zl6sdx6enIWIZGvinMS5ces5dkga9GYD0Www_CRAtghLYrqIHnQ0riMr16Ddn2sw9LbtvXmC_eBr8rkFG_Dbaz1N_t38nk3-pNP727-T8TTVgsmYMglZDjVKXhRlzmirqKaqyHhJmayB52VTZBpELiQtW4m6BQFlDbXkkDd5Jk6T0WHv2rvHHkOsViZotBY6dH2ouKAqo5wqMdDzD3Thet8N3w2KsVIJVbBB_Tgo7V0IHttq7c0K_K5itNqnUk3Ur9n_VO4GfHbAPug3956aeAGghos8</recordid><startdate>20191121</startdate><enddate>20191121</enddate><creator>Liu, Rongrong</creator><creator>Zhang, Wenhua</creator><creator>Wei, Donghui</creator><creator>Chen, Jing-Huo</creator><creator>Ng, Seik Weng</creator><creator>Yang, Guang</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-2820-282X</orcidid><orcidid>https://orcid.org/0000-0002-9766-6188</orcidid><orcidid>https://orcid.org/0000-0002-1379-0684</orcidid></search><sort><creationdate>20191121</creationdate><title>Adducts of triangular silver() 3,5-bis(trifluoromethyl)pyrazolate with thiophene derivatives: a weak interaction model of desulfurization</title><author>Liu, Rongrong ; Zhang, Wenhua ; Wei, Donghui ; Chen, Jing-Huo ; Ng, Seik Weng ; Yang, Guang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c314t-14a56abe42778610f90c097528014ba268d75ca363408f4ecfa3a8bab42a6d653</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Adducts</topic><topic>Adsorptivity</topic><topic>Benzothiophene</topic><topic>Crystallography</topic><topic>Desulfurizing</topic><topic>Dibenzothiophene</topic><topic>Interaction models</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Silver</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Rongrong</creatorcontrib><creatorcontrib>Zhang, Wenhua</creatorcontrib><creatorcontrib>Wei, Donghui</creatorcontrib><creatorcontrib>Chen, Jing-Huo</creatorcontrib><creatorcontrib>Ng, Seik Weng</creatorcontrib><creatorcontrib>Yang, Guang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Rongrong</au><au>Zhang, Wenhua</au><au>Wei, Donghui</au><au>Chen, Jing-Huo</au><au>Ng, Seik Weng</au><au>Yang, Guang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Adducts of triangular silver() 3,5-bis(trifluoromethyl)pyrazolate with thiophene derivatives: a weak interaction model of desulfurization</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><date>2019-11-21</date><risdate>2019</risdate><volume>48</volume><issue>43</issue><spage>16162</spage><epage>16166</epage><pages>16162-16166</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>-Acidic triangular silver(
i
) 3,5-bis(trifluoromethyl)pyrazolate (
Ag
3
pz
3
) can form 1:1 adducts with dibenzothiophene (DBT), 4,6-dimethyldibenzothiophene (DMDBT), benzothiophene (BT), and 2,5-dimethylthiophene (DMT), which are stabilized by weak AgS and AgC contacts and sometimes by stacking and, therefore, may represent a weak interaction model for some adsorptive desulfurization processes.
Triangular silver(
i
) 3,5-bis(trifluoromethyl)pyrazolate (
Ag
3
pz
3
) can quickly sequester dibenzothiophene (DBT) in isooctane, forming insoluble 1:1 adduct and thus possessing potential use in desulfurization technology.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/c9dt03344k</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-2820-282X</orcidid><orcidid>https://orcid.org/0000-0002-9766-6188</orcidid><orcidid>https://orcid.org/0000-0002-1379-0684</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2019-11, Vol.48 (43), p.16162-16166 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2309502093 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Adducts Adsorptivity Benzothiophene Crystallography Desulfurizing Dibenzothiophene Interaction models NMR Nuclear magnetic resonance Silver |
| title | Adducts of triangular silver() 3,5-bis(trifluoromethyl)pyrazolate with thiophene derivatives: a weak interaction model of desulfurization |
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