Ring Transformation of 1, 2, 3, 5, 6, 7-Hexahydropyrrolizinium Perchlorates into 1-Substituted 5-Oxo-perhydroazocines

A facile ring transformation of 1, 2, 3, 5, 6, 7-hexahydropyrrolizinium perchlorates (1 and 2) to 1-substituted 5-oxoperhydroazocines (5) is described. The spectroscopic and chemical properties of these products are also presented.

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1990/03/25, Vol.38(3), pp.577-580
Hauptverfasser: SUMOTO, Kunihiro, MIBU, Noboko, IRIE, Michiko, ABE, Nobuhiro, MIYANO, Seiji
Format: Artikel
Sprache:eng
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Zusammenfassung:A facile ring transformation of 1, 2, 3, 5, 6, 7-hexahydropyrrolizinium perchlorates (1 and 2) to 1-substituted 5-oxoperhydroazocines (5) is described. The spectroscopic and chemical properties of these products are also presented.
ISSN:0009-2363
1347-5223
DOI:10.1248/cpb.38.577