Ring Transformation of 1, 2, 3, 5, 6, 7-Hexahydropyrrolizinium Perchlorates into 1-Substituted 5-Oxo-perhydroazocines
A facile ring transformation of 1, 2, 3, 5, 6, 7-hexahydropyrrolizinium perchlorates (1 and 2) to 1-substituted 5-oxoperhydroazocines (5) is described. The spectroscopic and chemical properties of these products are also presented.
Gespeichert in:
| Veröffentlicht in: | Chemical & pharmaceutical bulletin 1990/03/25, Vol.38(3), pp.577-580 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 580 |
|---|---|
| container_issue | 3 |
| container_start_page | 577 |
| container_title | Chemical & pharmaceutical bulletin |
| container_volume | 38 |
| creator | SUMOTO, Kunihiro MIBU, Noboko IRIE, Michiko ABE, Nobuhiro MIYANO, Seiji |
| description | A facile ring transformation of 1, 2, 3, 5, 6, 7-hexahydropyrrolizinium perchlorates (1 and 2) to 1-substituted 5-oxoperhydroazocines (5) is described. The spectroscopic and chemical properties of these products are also presented. |
| doi_str_mv | 10.1248/cpb.38.577 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_jstag</sourceid><recordid>TN_cdi_proquest_journals_1460233961</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3132823411</sourcerecordid><originalsourceid>FETCH-LOGICAL-j1171-df0fc8ebc9ed3ee6e2aa9070d500f7afdcbb503356dd8c02e582a998afee88243</originalsourceid><addsrcrecordid>eNpFkF9LwzAUxYMoOKcvfoKAr83Mn6ZNH2WoEwYTnc8lTW-3lK2pSQrbPr3FCcLhnofzu_fCQeie0RnjqXo0fTUTaibz_AJNmEhzIjkXl2hCKS0IF5m4RjchtJRySXMxQcOH7TZ47XUXGuf3OlrXYddglmCeYJFgmeAswTlZwEFvj7V3_dF7t7Mn29lhj9_Bm-3OeR0hYNtFhxn5HKoQbRwi1FiS1cGRHvzvrj45YzsIt-iq0bsAd38-RV8vz-v5gixXr2_zpyVpGcsZqRvaGAWVKaAWABlwrQua01pS2uS6qU1VSSqEzOpaGcpBKq6LQukGQCmeiil6ON_tvfseIMSydYPvxpclSzPKhSgyNlLzM9WGqDdQ9t7utT-W2kdrdlCOpbJCqlKMOo-x3_90q30JnfgBckF08Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1460233961</pqid></control><display><type>article</type><title>Ring Transformation of 1, 2, 3, 5, 6, 7-Hexahydropyrrolizinium Perchlorates into 1-Substituted 5-Oxo-perhydroazocines</title><source>J-STAGE Free</source><source>EZB-FREE-00999 freely available EZB journals</source><source>Free Full-Text Journals in Chemistry</source><creator>SUMOTO, Kunihiro ; MIBU, Noboko ; IRIE, Michiko ; ABE, Nobuhiro ; MIYANO, Seiji</creator><creatorcontrib>SUMOTO, Kunihiro ; MIBU, Noboko ; IRIE, Michiko ; ABE, Nobuhiro ; MIYANO, Seiji</creatorcontrib><description>A facile ring transformation of 1, 2, 3, 5, 6, 7-hexahydropyrrolizinium perchlorates (1 and 2) to 1-substituted 5-oxoperhydroazocines (5) is described. The spectroscopic and chemical properties of these products are also presented.</description><identifier>ISSN: 0009-2363</identifier><identifier>EISSN: 1347-5223</identifier><identifier>DOI: 10.1248/cpb.38.577</identifier><language>eng</language><publisher>Tokyo: The Pharmaceutical Society of Japan</publisher><subject>1, 2, 3, 5, 6, 7-heyxahydropyrrolizinium perchlorate ; 1-substituted 5-oxoperhydroazocine ; 1H-NMR ; amide rotatinm barrier ; boat-chair conformaiton ; C-NMR ; synthesis ; transannular effect</subject><ispartof>Chemical and Pharmaceutical Bulletin, 1990/03/25, Vol.38(3), pp.577-580</ispartof><rights>The Pharmaceutical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 1990</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,1877,27901,27902</link.rule.ids></links><search><creatorcontrib>SUMOTO, Kunihiro</creatorcontrib><creatorcontrib>MIBU, Noboko</creatorcontrib><creatorcontrib>IRIE, Michiko</creatorcontrib><creatorcontrib>ABE, Nobuhiro</creatorcontrib><creatorcontrib>MIYANO, Seiji</creatorcontrib><title>Ring Transformation of 1, 2, 3, 5, 6, 7-Hexahydropyrrolizinium Perchlorates into 1-Substituted 5-Oxo-perhydroazocines</title><title>Chemical & pharmaceutical bulletin</title><addtitle>Chem. Pharm. Bull.</addtitle><description>A facile ring transformation of 1, 2, 3, 5, 6, 7-hexahydropyrrolizinium perchlorates (1 and 2) to 1-substituted 5-oxoperhydroazocines (5) is described. The spectroscopic and chemical properties of these products are also presented.</description><subject>1, 2, 3, 5, 6, 7-heyxahydropyrrolizinium perchlorate</subject><subject>1-substituted 5-oxoperhydroazocine</subject><subject>1H-NMR</subject><subject>amide rotatinm barrier</subject><subject>boat-chair conformaiton</subject><subject>C-NMR</subject><subject>synthesis</subject><subject>transannular effect</subject><issn>0009-2363</issn><issn>1347-5223</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNpFkF9LwzAUxYMoOKcvfoKAr83Mn6ZNH2WoEwYTnc8lTW-3lK2pSQrbPr3FCcLhnofzu_fCQeie0RnjqXo0fTUTaibz_AJNmEhzIjkXl2hCKS0IF5m4RjchtJRySXMxQcOH7TZ47XUXGuf3OlrXYddglmCeYJFgmeAswTlZwEFvj7V3_dF7t7Mn29lhj9_Bm-3OeR0hYNtFhxn5HKoQbRwi1FiS1cGRHvzvrj45YzsIt-iq0bsAd38-RV8vz-v5gixXr2_zpyVpGcsZqRvaGAWVKaAWABlwrQua01pS2uS6qU1VSSqEzOpaGcpBKq6LQukGQCmeiil6ON_tvfseIMSydYPvxpclSzPKhSgyNlLzM9WGqDdQ9t7utT-W2kdrdlCOpbJCqlKMOo-x3_90q30JnfgBckF08Q</recordid><startdate>19900325</startdate><enddate>19900325</enddate><creator>SUMOTO, Kunihiro</creator><creator>MIBU, Noboko</creator><creator>IRIE, Michiko</creator><creator>ABE, Nobuhiro</creator><creator>MIYANO, Seiji</creator><general>The Pharmaceutical Society of Japan</general><general>Japan Science and Technology Agency</general><scope>7TK</scope><scope>7TM</scope><scope>7U9</scope><scope>H94</scope></search><sort><creationdate>19900325</creationdate><title>Ring Transformation of 1, 2, 3, 5, 6, 7-Hexahydropyrrolizinium Perchlorates into 1-Substituted 5-Oxo-perhydroazocines</title><author>SUMOTO, Kunihiro ; MIBU, Noboko ; IRIE, Michiko ; ABE, Nobuhiro ; MIYANO, Seiji</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j1171-df0fc8ebc9ed3ee6e2aa9070d500f7afdcbb503356dd8c02e582a998afee88243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1990</creationdate><topic>1, 2, 3, 5, 6, 7-heyxahydropyrrolizinium perchlorate</topic><topic>1-substituted 5-oxoperhydroazocine</topic><topic>1H-NMR</topic><topic>amide rotatinm barrier</topic><topic>boat-chair conformaiton</topic><topic>C-NMR</topic><topic>synthesis</topic><topic>transannular effect</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>SUMOTO, Kunihiro</creatorcontrib><creatorcontrib>MIBU, Noboko</creatorcontrib><creatorcontrib>IRIE, Michiko</creatorcontrib><creatorcontrib>ABE, Nobuhiro</creatorcontrib><creatorcontrib>MIYANO, Seiji</creatorcontrib><collection>Neurosciences Abstracts</collection><collection>Nucleic Acids Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>AIDS and Cancer Research Abstracts</collection><jtitle>Chemical & pharmaceutical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>SUMOTO, Kunihiro</au><au>MIBU, Noboko</au><au>IRIE, Michiko</au><au>ABE, Nobuhiro</au><au>MIYANO, Seiji</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ring Transformation of 1, 2, 3, 5, 6, 7-Hexahydropyrrolizinium Perchlorates into 1-Substituted 5-Oxo-perhydroazocines</atitle><jtitle>Chemical & pharmaceutical bulletin</jtitle><addtitle>Chem. Pharm. Bull.</addtitle><date>1990-03-25</date><risdate>1990</risdate><volume>38</volume><issue>3</issue><spage>577</spage><epage>580</epage><pages>577-580</pages><issn>0009-2363</issn><eissn>1347-5223</eissn><abstract>A facile ring transformation of 1, 2, 3, 5, 6, 7-hexahydropyrrolizinium perchlorates (1 and 2) to 1-substituted 5-oxoperhydroazocines (5) is described. The spectroscopic and chemical properties of these products are also presented.</abstract><cop>Tokyo</cop><pub>The Pharmaceutical Society of Japan</pub><doi>10.1248/cpb.38.577</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0009-2363 |
| ispartof | Chemical and Pharmaceutical Bulletin, 1990/03/25, Vol.38(3), pp.577-580 |
| issn | 0009-2363 1347-5223 |
| language | eng |
| recordid | cdi_proquest_journals_1460233961 |
| source | J-STAGE Free; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| subjects | 1, 2, 3, 5, 6, 7-heyxahydropyrrolizinium perchlorate 1-substituted 5-oxoperhydroazocine 1H-NMR amide rotatinm barrier boat-chair conformaiton C-NMR synthesis transannular effect |
| title | Ring Transformation of 1, 2, 3, 5, 6, 7-Hexahydropyrrolizinium Perchlorates into 1-Substituted 5-Oxo-perhydroazocines |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-28T20%3A19%3A03IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_jstag&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ring%20Transformation%20of%201,%202,%203,%205,%206,%207-Hexahydropyrrolizinium%20Perchlorates%20into%201-Substituted%205-Oxo-perhydroazocines&rft.jtitle=Chemical%20&%20pharmaceutical%20bulletin&rft.au=SUMOTO,%20Kunihiro&rft.date=1990-03-25&rft.volume=38&rft.issue=3&rft.spage=577&rft.epage=580&rft.pages=577-580&rft.issn=0009-2363&rft.eissn=1347-5223&rft_id=info:doi/10.1248/cpb.38.577&rft_dat=%3Cproquest_jstag%3E3132823411%3C/proquest_jstag%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1460233961&rft_id=info:pmid/&rfr_iscdi=true |