Synthesis and absolute configuration of (+)-gonyauline: modulating substance of bioluminescent circadian rhythm in the unicellular alga Gonyaulax polyedra
Gonyauline, cis-2-(dimethylsulfonio)cyclopropanecarboxylate, an endogenous period-shortening substance of bioluminescent circadian rhythm of the dinoflagellate Gonyaulax polyedra was synthesized from (+)-2-methylthio-1,2-trans-cyclopropanedicarboyxlic acid (3a) and the absolute configuration was est...
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Veröffentlicht in: | Tetrahedron letters 1992-05, Vol.33 (20), p.2821-2822 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | Gonyauline, cis-2-(dimethylsulfonio)cyclopropanecarboxylate, an endogenous period-shortening substance of bioluminescent circadian rhythm of the dinoflagellate Gonyaulax polyedra was synthesized from (+)-2-methylthio-1,2-trans-cyclopropanedicarboyxlic acid (3a) and the absolute configuration was established as 1R,2R. |
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ISSN: | 0040-4039 1873-3581 |
DOI: | 10.1016/S0040-4039(00)78868-X |