Synthesis and absolute configuration of (+)-gonyauline: modulating substance of bioluminescent circadian rhythm in the unicellular alga Gonyaulax polyedra

Gonyauline, cis-2-(dimethylsulfonio)cyclopropanecarboxylate, an endogenous period-shortening substance of bioluminescent circadian rhythm of the dinoflagellate Gonyaulax polyedra was synthesized from (+)-2-methylthio-1,2-trans-cyclopropanedicarboyxlic acid (3a) and the absolute configuration was est...

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Veröffentlicht in:Tetrahedron letters 1992-05, Vol.33 (20), p.2821-2822
Hauptverfasser: Nakamura, H, Ohtoshi, M, Sampei, O, Akashi, Y, Murai, A
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Sprache:eng
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Zusammenfassung:Gonyauline, cis-2-(dimethylsulfonio)cyclopropanecarboxylate, an endogenous period-shortening substance of bioluminescent circadian rhythm of the dinoflagellate Gonyaulax polyedra was synthesized from (+)-2-methylthio-1,2-trans-cyclopropanedicarboyxlic acid (3a) and the absolute configuration was established as 1R,2R.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(00)78868-X