Synthesis and absolute configuration of (+)-gonyauline: modulating substance of bioluminescent circadian rhythm in the unicellular alga Gonyaulax polyedra
Gonyauline, cis-2-(dimethylsulfonio)cyclopropanecarboxylate, an endogenous period-shortening substance of bioluminescent circadian rhythm of the dinoflagellate Gonyaulax polyedra was synthesized from (+)-2-methylthio-1,2-trans-cyclopropanedicarboyxlic acid (3a) and the absolute configuration was est...
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| Veröffentlicht in: | Tetrahedron letters 1992-05, Vol.33 (20), p.2821-2822 |
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| container_issue | 20 |
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| container_title | Tetrahedron letters |
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| creator | Nakamura, H Ohtoshi, M Sampei, O Akashi, Y Murai, A |
| description | Gonyauline, cis-2-(dimethylsulfonio)cyclopropanecarboxylate, an endogenous period-shortening substance of bioluminescent circadian rhythm of the dinoflagellate Gonyaulax polyedra was synthesized from (+)-2-methylthio-1,2-trans-cyclopropanedicarboyxlic acid (3a) and the absolute configuration was established as 1R,2R. |
| doi_str_mv | 10.1016/S0040-4039(00)78868-X |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0040-4039 |
| ispartof | Tetrahedron letters, 1992-05, Vol.33 (20), p.2821-2822 |
| issn | 0040-4039 1873-3581 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_5337387 |
| source | Elsevier ScienceDirect Journals |
| subjects | algae and seaweeds Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids chemical constituents of plants Chemistry Exact sciences and technology Organic chemistry period shortening substances Preparations and properties stereochemistry synthesis |
| title | Synthesis and absolute configuration of (+)-gonyauline: modulating substance of bioluminescent circadian rhythm in the unicellular alga Gonyaulax polyedra |
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