2,6-Bis(5,6-diisopropyl-1,2,4-triazin-3-yl)pyridine: a highly selective N-donor ligand studied by TRLFS, liquid–liquid extraction and molecular dynamics

The complexation of Cm( iii ) and Eu( iii ) with 2,6-bis(5,6-di-i-propyl-1,2,4-triazin-3-yl)-pyridine ( i Pr-BTP) is studied in methanol : water (1 : 1, vol) by time-resolved laser-induced fluorescence spectroscopy (TRLFS). With increasing ligand concentration [Cm( i Pr-BTP) 3 ] 3+ and [Eu( i Pr-BTP...

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Veröffentlicht in:New journal of chemistry 2016, Vol.40 (12), p.10389-10397
Hauptverfasser: Beele, Björn B., Skerencak-Frech, Andrej, Stein, Arnulf, Trumm, Michael, Wilden, Andreas, Lange, Steve, Modolo, Giuseppe, Müllich, Udo, Schimmelpfennig, Bernd, Geist, Andreas, Panak, Petra J.
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Sprache:eng
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