A Direct Synthesis of Symmetrical (E,E)-1,4-Diaryl-1,3-butadienes by Wenkert Arylation of Thiophene
The nickel‐catalyzed coupling of thiophene with aryl Grignard reagents (Wenkert reaction) is accelerated by N‐heterocyclic carbene or trialkylphosphane ligands, providing a general, scalable direct synthesis of symmetrical 1,4‐diarylbutadienes.
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Veröffentlicht in: | Advanced synthesis & catalysis 2010-10, Vol.352 (14-15), p.2411-2415 |
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container_title | Advanced synthesis & catalysis |
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creator | Hintermann, Lukas Schmitz, Marco Chen, Yun |
description | The nickel‐catalyzed coupling of thiophene with aryl Grignard reagents (Wenkert reaction) is accelerated by N‐heterocyclic carbene or trialkylphosphane ligands, providing a general, scalable direct synthesis of symmetrical 1,4‐diarylbutadienes. |
doi_str_mv | 10.1002/adsc.201000350 |
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subjects | alkenes cross-coupling homogeneous catalysis nickel sulfur heterocycles |
title | A Direct Synthesis of Symmetrical (E,E)-1,4-Diaryl-1,3-butadienes by Wenkert Arylation of Thiophene |
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