Chlorido(6‐diphenyl­phosphino‐2‐pyridonato‐κ2P,N)(6‐diphenyl­phosphino‐2‐hydroxypyridine‐κ2P,N)hydridoiridium(III) chloro­form 1.896‐solvate

Chlorido(6‐diphenyl­phosphino‐2‐pyridonato‐κ2P,N)(6‐diphenyl­phosphino‐2‐hydroxypyridine‐κ2P,N)hydridoiridium(III) chloro­form 1.896‐solvate

The title complex, [Ir(C17H13NOP)ClH(C17H14NOP)]·1.896CHCl3, contains hydride, chloride, 6‐diphenyl­phosphino‐2‐hydroxy­pyridine (pyphosH) and 6‐diphenyl­phosphino‐2‐pyridonate (pyphos) ligands coordinated to an IrIII metal centre to give a distorted octa­hedral coordination geometry. The two P and...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2007-02, Vol.63 (2), p.m576-m578
Hauptverfasser: Hara, Takeshi, Miyabayashi, Takayuki, Yamagata, Tsuneaki, Mashima, Kazushi
Format: Artikel
Sprache:eng
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Zusammenfassung:The title complex, [Ir(C17H13NOP)ClH(C17H14NOP)]·1.896CHCl3, contains hydride, chloride, 6‐diphenyl­phosphino‐2‐hydroxy­pyridine (pyphosH) and 6‐diphenyl­phosphino‐2‐pyridonate (pyphos) ligands coordinated to an IrIII metal centre to give a distorted octa­hedral coordination geometry. The two P and two N atoms of the pyphosH and pyphos ligands lie with a cis coordination in the equatorial plane. An intra­molecular O—H⋯O hydrogen bond is observed between the pyphosH and pyphos ligands.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807002462