Tris(2‐N‐methyl­amino­carbonyl‐3‐hydr­oxy‐1,6‐dimethyl‐1,4‐dihydro‐4‐pyridinonato)­iron(III) dimethyl­formamide disolvate

Tris(2‐N‐methyl­amino­carbonyl‐3‐hydr­oxy‐1,6‐dimethyl‐1,4‐dihydro‐4‐pyridinonato)­iron(III) dimethyl­formamide disolvate

In the crystal structure of the title compound, Fe(C9H11N2O3)3·2C3H7NO, the FeIII ion is six‐coordinate with a distorted octa­hedral configuration consisting of six donor O atoms from three bidentate ligands. Two of the amide NH groups are involved in intra­molecular N—H⋯Op (p = phenolic) hydrogen b...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2005-10, Vol.61 (10), p.m2055-m2057
Hauptverfasser: Tam, Tim F., Leung‐Toung, Regis, Wang, Yingsheng, Spino, Michael, Williams, Glenn, Lough, Alan J.
Format: Artikel
Sprache:eng
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Zusammenfassung:In the crystal structure of the title compound, Fe(C9H11N2O3)3·2C3H7NO, the FeIII ion is six‐coordinate with a distorted octa­hedral configuration consisting of six donor O atoms from three bidentate ligands. Two of the amide NH groups are involved in intra­molecular N—H⋯Op (p = phenolic) hydrogen bonds, while the third is involved in forming centrosymmetric dimers via inter­molecular N—H⋯Op hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536805029776