Diaquabis(nitrato‐κO)bis(4,7‐dihydro‐1,2,4‐triazolo[1,5‐a]pyrimidin‐7‐one‐κN3)copper(II)
The molecule of the title compound, [Cu(7HtpO)2(NO3)2(H2O)2], contains two neutral 4,7‐dihydro‐1,2,4‐triazolo[1,5‐a]pyrimidin‐7‐one (7HtpO) ligands , coordinated through the N atom in position 3, two nitrate ions each coordinated through one of the O atoms, and two water molecules, completing...
Gespeichert in:
Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2003-10, Vol.59 (10), p.m903-m905 |
---|---|
Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | The molecule of the title compound, [Cu(7HtpO)2(NO3)2(H2O)2], contains two neutral 4,7‐dihydro‐1,2,4‐triazolo[1,5‐a]pyrimidin‐7‐one (7HtpO) ligands , coordinated through the N atom in position 3, two nitrate ions each coordinated through one of the O atoms, and two water molecules, completing the octahedral environment around the copper atom which lies on an inversion centre, thus defining the all‐trans isomer. The intramolecular N—H⋯O hydrogen bond involving the nitrate oxygen atom linked to the metal atom stabilizes the structure. Distances in the coordination sphere are Cu—N(7HtpO)= 2.003 (2), Cu—O(nitrate) = 2.410 (2) and Cu—O(water) = 1.977 (2) Å. |
---|---|
ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536803019974 |