Di­aqua­bis­(nitrato‐κO)­bis(4,7‐di­hydro‐1,2,4‐triazolo[1,5‐a]­pyrimidin‐7‐one‐κN3)copper(II)

The molecule of the title compound, [Cu(7HtpO)2(NO3)2(H2O)2], contains two neutral 4,7‐di­hydro‐1,2,4‐triazolo­[1,5‐a]­pyrimidin‐7‐one (7HtpO) ligands , coord­in­ated through the N atom in position 3, two nitrate ions each coordinated through one of the O atoms, and two water mol­ecules, completing...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2003-10, Vol.59 (10), p.m903-m905
Hauptverfasser: Abul‐Haj, Mohammad, Quirós, Miguel, Salas, Juan M.
Format: Artikel
Sprache:eng
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Zusammenfassung:The molecule of the title compound, [Cu(7HtpO)2(NO3)2(H2O)2], contains two neutral 4,7‐di­hydro‐1,2,4‐triazolo­[1,5‐a]­pyrimidin‐7‐one (7HtpO) ligands , coord­in­ated through the N atom in position 3, two nitrate ions each coordinated through one of the O atoms, and two water mol­ecules, completing the octahedral environment around the copper atom which lies on an inversion centre, thus defining the all‐trans isomer. The intramolecular N—H⋯O hydrogen bond involving the nitrate oxy­gen atom linked to the metal atom stabilizes the structure. Distances in the coordination sphere are Cu—N(7HtpO)= 2.003 (2), Cu—O(nitrate) = 2.410 (2) and Cu—O(water) = 1.977 (2) Å.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536803019974