A dithietane of 2‐methyl­propane­di­thio­ic acid

A dithietane of 2‐methyl­propane­di­thio­ic acid

Under the action of BF3·Me2O, 2‐methyl­propane­di­thio­ic acid does not give the expected adamantanoid product but the trans‐2,4‐diiso­propyl‐2,4‐bis­[(2‐methyl‐1‐thio­xo)­propyl­sulf­an­yl]‐1,3‐dithietane. The X‐ray structure of the centrosymmetric title compound confirms the trans conformation of...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2003-04, Vol.59 (4), p.o545-o546
Hauptverfasser: Mahjoub, Ahmed, Zantour, Hédi, Masson, Serge, Saquet, Monique, Averbuch‐Pouchot, Marie‐Thérèse
Format: Artikel
Sprache:eng
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Zusammenfassung:Under the action of BF3·Me2O, 2‐methyl­propane­di­thio­ic acid does not give the expected adamantanoid product but the trans‐2,4‐diiso­propyl‐2,4‐bis­[(2‐methyl‐1‐thio­xo)­propyl­sulf­an­yl]‐1,3‐dithietane. The X‐ray structure of the centrosymmetric title compound confirms the trans conformation of the dithietane mol­ecule.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536803003167