Lithium trifluoromethanesulfonate acetonitrile adduct
The title compound, poly[[(acetonitrile)lithium(I)]‐μ‐triflato], [Li(CF3O3S)(C2H3N)]∞, was synthesized by reaction of LiCF3SO3 with CH3CN and is found to exist as a one‐dimensional polymer in the solid state. Each Li+ cation is tetrahedrally coordinated by three oxygen donors from three differen...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2002-05, Vol.58 (5), p.m176-m177 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The title compound, poly[[(acetonitrile)lithium(I)]‐μ‐triflato], [Li(CF3O3S)(C2H3N)]∞, was synthesized by reaction of LiCF3SO3 with CH3CN and is found to exist as a one‐dimensional polymer in the solid state. Each Li+ cation is tetrahedrally coordinated by three oxygen donors from three different CF3SO3− anions [Li—O = 1.925 (3), 1.926 (3) and 1.940 (2) Å] and one CH3CN nitrogen donor [Li—N = 2.042 (3) Å]. The unit cell has a β angle of 90.064 (3)°, but the Laue symmetry is 2/m. As a result of this, the crystals exist as pseudo‐merohedral twins related by the twin law (00/00/001). |
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| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536802005895 |