exo‐(±)‐Tri­carbonyl(η6‐1‐hydroxy‐1,2‐di­hydro­ace­naphthyl­ene)­chromium(0)

The crystal structure of the title compound, [Cr(C12H10O)(CO)3], contains two conformers in an asymmetric unit. The projection of the Cr(CO)3 unit on the arene ring is staggered in one conformer, whereas it is about midway between staggered and eclipsed in the other. In both conformers, the Cr(CO)3...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2001-05, Vol.57 (5), p.m204-m206
Hauptverfasser: Parvez, Masood, Simion, Dan V., Sorensen, Ted S.
Format: Artikel
Sprache:eng
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Zusammenfassung:The crystal structure of the title compound, [Cr(C12H10O)(CO)3], contains two conformers in an asymmetric unit. The projection of the Cr(CO)3 unit on the arene ring is staggered in one conformer, whereas it is about midway between staggered and eclipsed in the other. In both conformers, the Cr(CO)3 unit is slightly displaced relative to the center of the arene ring. The hydroxyl groups are involved in hydrogen bonding between the conformers lying about glide planes, with O⋯O distances of 2.835 (8) and 2.771 (8) Å, resulting in chains along the a axis.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536801006304