1‐Methylindole‐3‐carboxaldehyde oxime derivatives
1‐Methylindole‐3‐carboxaldehyde oxime, C10H10N2O, (I),and (E)‐5‐methoxy‐1‐methylindole‐3‐carboxaldehyde oxime, C11H12N2O2, (II), were examined structurally to ascertain the geometry of the hydroxyimino function relative to the indole core. Oxime (I) exhibits cis geometry and there are two mol...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2001-01, Vol.57 (1), p.58-61 |
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| container_title | Acta crystallographica. Section C, Crystal structure communications |
| container_volume | 57 |
| creator | Janes, Robert W. Potter, Brian S. Naylor, Matthew A. Ferguson, Amanda C. Patel, Kantilal B. Stratford, Michael R. L. Wardman, Peter Everett, Steven A. |
| description | 1‐Methylindole‐3‐carboxaldehyde oxime, C10H10N2O, (I),and (E)‐5‐methoxy‐1‐methylindole‐3‐carboxaldehyde oxime, C11H12N2O2, (II), were examined structurally to ascertain the geometry of the hydroxyimino function relative to the indole core. Oxime (I) exhibits cis geometry and there are two molecules in the asymmetric unit. In contrast, oxime (II) exhibits trans geometry and has four molecules in the asymmetric unit, with the geometry of the 5‐methoxy group in one molecule differing from that in the other three. Both crystal structures are maintained by hydrogen bonding with no π‐stacking of the indole moiety present. |
| doi_str_mv | 10.1107/S0108270100005795 |
| format | Article |
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L. ; Wardman, Peter ; Everett, Steven A.</creator><creatorcontrib>Janes, Robert W. ; Potter, Brian S. ; Naylor, Matthew A. ; Ferguson, Amanda C. ; Patel, Kantilal B. ; Stratford, Michael R. L. ; Wardman, Peter ; Everett, Steven A.</creatorcontrib><description>1‐Methylindole‐3‐carboxaldehyde oxime, C10H10N2O, (I),and (E)‐5‐methoxy‐1‐methylindole‐3‐carboxaldehyde oxime, C11H12N2O2, (II), were examined structurally to ascertain the geometry of the hydroxyimino function relative to the indole core. Oxime (I) exhibits cis geometry and there are two molecules in the asymmetric unit. In contrast, oxime (II) exhibits trans geometry and has four molecules in the asymmetric unit, with the geometry of the 5‐methoxy group in one molecule differing from that in the other three. Both crystal structures are maintained by hydrogen bonding with no π‐stacking of the indole moiety present.</description><identifier>ISSN: 0108-2701</identifier><identifier>EISSN: 1600-5759</identifier><identifier>DOI: 10.1107/S0108270100005795</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: Munksgaard International Publishers</publisher><ispartof>Acta crystallographica. 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L.</creatorcontrib><creatorcontrib>Wardman, Peter</creatorcontrib><creatorcontrib>Everett, Steven A.</creatorcontrib><title>1‐Methylindole‐3‐carboxaldehyde oxime derivatives</title><title>Acta crystallographica. Section C, Crystal structure communications</title><description>1‐Methylindole‐3‐carboxaldehyde oxime, C10H10N2O, (I),and (E)‐5‐methoxy‐1‐methylindole‐3‐carboxaldehyde oxime, C11H12N2O2, (II), were examined structurally to ascertain the geometry of the hydroxyimino function relative to the indole core. Oxime (I) exhibits cis geometry and there are two molecules in the asymmetric unit. In contrast, oxime (II) exhibits trans geometry and has four molecules in the asymmetric unit, with the geometry of the 5‐methoxy group in one molecule differing from that in the other three. 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Section C, Crystal structure communications</jtitle><date>2001-01</date><risdate>2001</risdate><volume>57</volume><issue>1</issue><spage>58</spage><epage>61</epage><pages>58-61</pages><issn>0108-2701</issn><eissn>1600-5759</eissn><abstract>1‐Methylindole‐3‐carboxaldehyde oxime, C10H10N2O, (I),and (E)‐5‐methoxy‐1‐methylindole‐3‐carboxaldehyde oxime, C11H12N2O2, (II), were examined structurally to ascertain the geometry of the hydroxyimino function relative to the indole core. Oxime (I) exhibits cis geometry and there are two molecules in the asymmetric unit. In contrast, oxime (II) exhibits trans geometry and has four molecules in the asymmetric unit, with the geometry of the 5‐methoxy group in one molecule differing from that in the other three. Both crystal structures are maintained by hydrogen bonding with no π‐stacking of the indole moiety present.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>Munksgaard International Publishers</pub><doi>10.1107/S0108270100005795</doi></addata></record> |
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| ispartof | Acta crystallographica. Section C, Crystal structure communications, 2001-01, Vol.57 (1), p.58-61 |
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| source | Crystallography Journals Online; Wiley Online Library All Journals |
| title | 1‐Methylindole‐3‐carboxaldehyde oxime derivatives |
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