1‐Methyl­indole‐3‐carbox­aldehyde oxime derivatives

1‐Methyl­indole‐3‐carbox­aldehyde oxime, C10H10N2O, (I),and (E)‐5‐methoxy‐1‐methyl­indole‐3‐carbox­aldehyde oxime, C11H12N2O2, (II), were ex­amined structurally to ascertain the geometry of the hydroxy­imino function relative to the indole core. Oxime (I) exhibits cis geometry and there are two mol­...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2001-01, Vol.57 (1), p.58-61
Hauptverfasser: Janes, Robert W., Potter, Brian S., Naylor, Matthew A., Ferguson, Amanda C., Patel, Kantilal B., Stratford, Michael R. L., Wardman, Peter, Everett, Steven A.
Format: Artikel
Sprache:eng
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Zusammenfassung:1‐Methyl­indole‐3‐carbox­aldehyde oxime, C10H10N2O, (I),and (E)‐5‐methoxy‐1‐methyl­indole‐3‐carbox­aldehyde oxime, C11H12N2O2, (II), were ex­amined structurally to ascertain the geometry of the hydroxy­imino function relative to the indole core. Oxime (I) exhibits cis geometry and there are two mol­ecules in the asymmetric unit. In contrast, oxime (II) exhibits trans geometry and has four mol­ecules in the asymmetric unit, with the geometry of the 5‐methoxy group in one mol­ecule differing from that in the other three. Both crystal structures are maintained by hydrogen bonding with no π‐stacking of the indole moiety present.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270100005795