Structural and Magnetic Properties of Pr2BaCuO5 Oxide

The Pr2BaCuO5 oxide has been prepared by using a precursor method. X‐ray and neutron diffraction data reveal that this mixed oxide crystallizes with the so‐called Nd2BaPtO5‐type structure, showing tetragonal symmetry and space group P4/mbm. Magnetic susceptibility, magnetization and specific heat me...

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Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2007-11, Vol.633 (15), p.2654-2657
Hauptverfasser: Pascual, E. Climent, de Paz, J. Romero, Puche, Regino Sáez
Format: Artikel
Sprache:eng
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Zusammenfassung:The Pr2BaCuO5 oxide has been prepared by using a precursor method. X‐ray and neutron diffraction data reveal that this mixed oxide crystallizes with the so‐called Nd2BaPtO5‐type structure, showing tetragonal symmetry and space group P4/mbm. Magnetic susceptibility, magnetization and specific heat measurements reveal that Pr2BaCuO5 oxide behaves as antiferromagnet, where the Pr3+ and Cu2+ sublattices become simultaneously ordered at 15 K. Preliminary neutron diffraction studies confirm this proposed antiferromagnetic ordering and it can be described by the wave vector k = [0,0,0].
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200700361