Crystal Structure of LiClO4

Crystal Structure of LiClO4

Single crystals of LiClO4 were obtained during attempts to prepare lithium containing rare earth perchlorates from a lithium perchlorate melt. In the crystal structure of LiClO4 (ortho‐rhombic, Pnma, Z =4, a = 865.7(1), b = 691.29(9) pm, c = 483.23(6), Rall = 0.0273) the Li+ ions are in distorted oc...

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Veröffentlicht in:Zeitschrift für anorganische und allgemeine Chemie (1950) 2003-08, Vol.629 (9), p.1466-1468
1. Verfasser: Wickleder, Mathias S.
Format: Artikel
Sprache:eng
Schlagworte:
Crystal Structure
Lithium
Perchlorates
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Zusammenfassung:Single crystals of LiClO4 were obtained during attempts to prepare lithium containing rare earth perchlorates from a lithium perchlorate melt. In the crystal structure of LiClO4 (ortho‐rhombic, Pnma, Z =4, a = 865.7(1), b = 691.29(9) pm, c = 483.23(6), Rall = 0.0273) the Li+ ions are in distorted octahedral coordination of oxygen atoms. The octahedra are linked via common edges to chains according to 1[LiO2/1O4/2] which run in the [010] direction. The perchlorate ions are almost ideal tetrahedra.
ISSN:0044-2313
1521-3749
DOI:10.1002/zaac.200300114