Support Nano‐Co/CeO2‐δ Catalyst for CO2 Hydromethanation

The large‐scale use of fossil fuels had resulted in massive emission of CO2 and a series of serious environmental problems, which directly threatening human survival and sustainable development. CO2 is also the abundant carbon resource in C1 family. CO2 catalytic hydrogenation to CH4 is one of the effective ways to ultilize CO2 with low energy and high efficiency, which has been widely concerned in recent years. Suppoted nano‐Co/CeO2‐δ catalysts were prepared and evaluated their CO2 hydrogenation performances. XRD, H2‐TPR, H2‐TPD and CO2‐TPD had been conducted to study the physicochemical properties of the prepared Co/CeO2‐δ catalysts. The Co loading significantly affects the physicochemical properties and CO2 hydrogenation performances. The active metal Co species were highly diepersed on the CeO2 support surface. The number of active metal Co species, which formed by H2 reduction, increased with the increasing of Co loading. And the ability to adsorb and activate the reactant H2 and CO2 molecules was also enhanced, which effectively promoted the CO2 hydrogenation performances. Among of the studied Co/CeO2‐δ catalysts, the CoCe09 catalyst with Co loading of 9 % showed the best CO2 catalytic hydrogenation activity. In the reaction temperature of 240–400 °C, the CO2 conversion and CH4 selectivity follow the order: CoCe01