Eine einfache Berechnungsmethode zur Abschätzung des induktiven Effekts verschiedenartiger komplexer Substituenten
A Simple Calculation Method for the Estimation of the Inductive Effect of Different Substituents A new method without great mathematical operations for the estimation of the inductive effect of any substituents is described. The starting values are the electronegativities and the bond lengths of the...
Gespeichert in:
Veröffentlicht in: | Journal für Praktische Chemie 1978, Vol.320 (2), p.249-254 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | A Simple Calculation Method for the Estimation of the Inductive Effect of Different Substituents
A new method without great mathematical operations for the estimation of the inductive effect of any substituents is described. The starting values are the electronegativities and the bond lengths of the atoms of the corresponding substituent.
The ID values, received by this method show a good correlation with the known electronic parameters (F, σ′, σ*, σI and σ qI) and with the velocity constants and equilibrium constants of chemical reactions, respectively. |
---|---|
ISSN: | 0021-8383 1521-3897 |
DOI: | 10.1002/prac.19783200211 |