Self‐Assembled PMMA Porous Membranes Decorated with In Situ Synthesized ZnO Nanoparticles with UV‐Tunable Wettability

This study reports a simple approach to fabricate porous poly(methyl methacrylate) (PMMA) membranes homogeneously decorated with exposed zinc oxide (ZnO) nanoparticles (NPs). This fabrication method significantly overcomes the disadvantages of both conventional foaming processes and incorporation of inorganic NPs in polymeric matrices. In particular, the porous structure is simply self‐assembled by slowly evaporating a suitable solvent. The ZnO NPs are in situ formed by a thermally activated conversion of the zinc acetate precursor, previously embedded in the polymeric matrix. Scanning and transmission electron microscopy investigations show the formation of the desired self‐assembled highly porous structure and ZnO NPs with branched morphology, respectively. The wetting behavior of the membranes surface is studied as a function of the ZnO content and UV irradiation, exploiting the switchable wettability of ZnO. The obtained unexpected results are then tentatively rationalized taking into account the surface chemistry and the roughness that arises from both porous structure and the different NPs dimensions and content. Facile two‐step method to fabricate porous poly(methyl methacrylate) (PMMA) membranes homogeneously decorated with exposed zinc oxide nanoparticles in situ formed directly in the solid polymeric structure by a thermally induced solid‐state reaction.