Front Cover: Heterobimetallic Carbene Complexes Bearing Cyclometalated IrIII/RhIII and Mixed NHC∧ Py/PPh3 Coordinated PdII Centers: Structures and Tandem Catalysis (Eur. J. Inorg. Chem. 12/2021)
The Front Cover shows the combined action of two different metal centers in heterobimetallic MIII−PdII (M=Rh, Ir) complexes, featuring cyclometalated MIII and mixed NHC∧ Py/PPh3 coordinated PdII centers, during tandem Suzuki‐Miyaura/transfer hydrogenation reactions. The heterobimetallic complex, bea...
Gespeichert in:
Veröffentlicht in: | European journal of inorganic chemistry 2021-03, Vol.2021 (12), p.1103-1103 |
---|---|
Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | The Front Cover shows the combined action of two different metal centers in heterobimetallic MIII−PdII (M=Rh, Ir) complexes, featuring cyclometalated MIII and mixed NHC∧
Py/PPh3 coordinated PdII centers, during tandem Suzuki‐Miyaura/transfer hydrogenation reactions. The heterobimetallic complex, bearing cyclometalated IrIII and mixed NHC∧
PPh3 donor ligands at the PdII center, shows excellent selectivity for 4‐biphenylmethanol in the tandem reaction. More information can be found in the Full Paper by R. Maity and co‐workers. |
---|---|
ISSN: | 1434-1948 1099-0682 |
DOI: | 10.1002/ejic.202100135 |