First Tetranuclear CoII Cluster with Planar Triangular Pattern: Crystal Structure and Ferromagnetic Behavior

First Tetranuclear CoII Cluster with Planar Triangular Pattern: Crystal Structure and Ferromagnetic Behavior

The preparation, crystal structure and magnetic properties of the first tetrameric CoII cluster with a unique planar triangular motif, [Co4L3(H2O)2](ClO4)2·2H2O (1), based on a carboxylic‐functionalized 1,5‐diazacyclooctane (DACO) bridging ligand [1,5‐bis(2‐carboxyethyl)‐DACO], are reported. (© Wile...

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Veröffentlicht in:European journal of inorganic chemistry 2004-08, Vol.2004 (16), p.3228-3231
Hauptverfasser: Du, Miao, Guo, Ya-Mei, Bu, Xian-He, Ribas, Joan
Format: Artikel
Sprache:eng
Schlagworte:
Carboxylic-functionalized diazamesocyclic ligands
Cobalt
Crystal structure
Magnetic properties
Tetranuclear clusters
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Zusammenfassung:The preparation, crystal structure and magnetic properties of the first tetrameric CoII cluster with a unique planar triangular motif, [Co4L3(H2O)2](ClO4)2·2H2O (1), based on a carboxylic‐functionalized 1,5‐diazacyclooctane (DACO) bridging ligand [1,5‐bis(2‐carboxyethyl)‐DACO], are reported. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.200400274