Designed Assembly of Low-dimensional Molecular Units: Novel Neutral Coordination Polymers Based on (Phosphonodithioato)NiII Complexes

Designed Assembly of Low-dimensional Molecular Units: Novel Neutral Coordination Polymers Based on (Phosphonodithioato)NiII Complexes

The reactions of phosphonodithioato complexes [Ni(ROdtp)2] [where ROdtp = (4‐MeOPh)(RO)PS2; R = Et, Me] with 4,4′‐bipy and N,N′‐bis‐(3‐pyridinylmethylene)benzene‐1,4‐diamine (bdpy), respectively, yield the 1:1 coordination polymers [Ni(EtOdtp)2(bipy)]8 and [Ni(MeOdtp)2(bdpy)]∞, whose syntheses and s...

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Veröffentlicht in:European journal of inorganic chemistry 2004-05, Vol.2004 (10), p.2008-2012
Hauptverfasser: Aragoni, M. Carla, Arca, Massimiliano, Champness, Neil R., Chernikov, Aleksey V., Devillanova, Francesco A., Isaia, Francesco, Lippolis, Vito, Oxtoby, Neil S., Verani, Gaetano, Vatsadze, Sergey Z., Wilson, Claire
Format: Artikel
Sprache:eng
Schlagworte:
Bipyridyl ligands
Coordination polymers
Crystal engineering
Phosphonodithioates
X-ray diffraction
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Zusammenfassung:The reactions of phosphonodithioato complexes [Ni(ROdtp)2] [where ROdtp = (4‐MeOPh)(RO)PS2; R = Et, Me] with 4,4′‐bipy and N,N′‐bis‐(3‐pyridinylmethylene)benzene‐1,4‐diamine (bdpy), respectively, yield the 1:1 coordination polymers [Ni(EtOdtp)2(bipy)]8 and [Ni(MeOdtp)2(bdpy)]∞, whose syntheses and single‐crystal X‐ray diffraction analyses are reported. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.200400089