A Twofold Interpenetrated Metal-Organic Framework with High Performance in Selective Separation of C2H2/CH4

A twofold interpenetrated metal–organic framework, PMOF‐3, composed of four kinds of polyhedra exhibits the highest selectivity of 157 for C2H2/CH4 separation at 296 K and 1 atm owing to the synergistic effect of the open metal sites, C≡C triple bonds, and microporous structure. Let gas in! A twofol...

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Veröffentlicht in:	ChemPlusChem (Weinheim, Germany) Germany), 2016-08, Vol.81 (8), p.770-774
Hauptverfasser:	Alduhaish, Osamah, Wang, Hailong, Li, Bin, Hu, Tong-Liang, Arman, Hadi D., Alfooty, Khalid, Chen, Banglin
Format:	Artikel
Sprache:	eng
Schlagworte:	Adsorbents Adsorption Carbon dioxide Chemistry Crystal structure Fossil fuels Gas separation Gases metal-organic frameworks microporous materials Natural gas noncovalent interactions Polyhedra structure-activity relationships
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Zusammenfassung:	A twofold interpenetrated metal–organic framework, PMOF‐3, composed of four kinds of polyhedra exhibits the highest selectivity of 157 for C2H2/CH4 separation at 296 K and 1 atm owing to the synergistic effect of the open metal sites, C≡C triple bonds, and microporous structure. Let gas in! A twofold interpenetrated metal–organic framework, PMOF‐3, composed of four kinds of polyhedra exhibits a high selectivity of 157 for C2H2/CH4 separation at 296 K and 1 atm owing to the synergistic effect of the open metal sites, C≡C triple bonds, and microporous structure (see figure).
ISSN:	2192-6506 2192-6506
DOI:	10.1002/cplu.201600194