ChemInform Abstract: Organocatalytic Peroxidation of Malonates, β‐Ketoesters, and Cyanoacetic Esters Using n‐Bu4NI/t‐BuOOH‐Mediated Intermolecular Oxidative C(sp3)—O Coupling

The scalable title transformation of malonates succeeds in high yields whereas the reaction of β‐ketoesters and cyanoacetic esters delivers only low to moderate product yields.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2016-02, Vol.47 (10), p.no-no
Hauptverfasser:	Terent'ev, Alexander O., Zdvizhkov, Alexander T., Levitsky, Dmitri O., Fleury, Fabrice, Pototskiy, Roman A., Kulakova, Alena N., Nikishin, Gennady I.
Format:	Artikel
Sprache:	eng
Schlagworte:	carboxylic acid esters (acyclic compounds) per‐compounds (acyclic compounds)
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The scalable title transformation of malonates succeeds in high yields whereas the reaction of β‐ketoesters and cyanoacetic esters delivers only low to moderate product yields.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201610061