ChemInform Abstract: Synthesis of (Z)-Organylthioenynes Using KF/Al2O3/Solvent as Recyclable System

Alumina‐supported KF‐promoted hydrothiolation of 1,3‐butadiynes in PEG‐400 or glycerol efficiently affords thiobutenynes with clear to complete (Z)‐selectivity.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2011-04, Vol.42 (14), p.no-no
Hauptverfasser:	Alves, Diego, Sachini, Maraisa, Jacob, Raquel G., Lenardao, Eder J., Contreira, Maria E., Savegnago, Lucielli, Perin, Gelson
Format:	Artikel
Sprache:	eng
Schlagworte:	addition reactions mercaptans mercaptans, thioethers (acyclic compounds) mercaptans, thioethers (benzene compounds) thioethers (acyclic compounds) thioethers (benzene compounds)
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Beschreibung
Zusammenfassung:	Alumina‐supported KF‐promoted hydrothiolation of 1,3‐butadiynes in PEG‐400 or glycerol efficiently affords thiobutenynes with clear to complete (Z)‐selectivity.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201114090