Synthesis, Structure, and Electrical Properties of Ta4FeTe4

Ta4FeTe4 has been synthesized and its structure determined by single‐crystal X‐ray methods. It crystallizes in the ortho‐rhombic space group Pbam with Z = 4 and a = 10.514(5), b = 18.275(7), and c = 4.815(1) Å. Ta4FeTe4 has a chain structure built up by Fe‐centered Ta8‐square antiprisms sharing comm...

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Veröffentlicht in:Chemische Berichte 1995-06, Vol.128 (6), p.569-573
Hauptverfasser: Neuhausen, Jörg, Finckh, Ernst Wolfgang, Tremel, Wolfgang
Format: Artikel
Sprache:eng
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Zusammenfassung:Ta4FeTe4 has been synthesized and its structure determined by single‐crystal X‐ray methods. It crystallizes in the ortho‐rhombic space group Pbam with Z = 4 and a = 10.514(5), b = 18.275(7), and c = 4.815(1) Å. Ta4FeTe4 has a chain structure built up by Fe‐centered Ta8‐square antiprisms sharing common square faces. The resistivity of Ta4FeTe4 has been measured by a two‐point method. Ta4FeTe4 shows metallic behavior. The structure of Ta4FeTe4 is discussed in relation to other early transition metal cluster compounds. A rational approach to the synthesis of related compounds is proposed.
ISSN:0009-2940
1099-0682
DOI:10.1002/cber.19951280608