1H‐CIDNP bei einer Insertionsreaktion von Dimethylsilylenen

1H‐CIDNP During an Insertion Reaction of Dimethylsilylenes During the reaction of photochemically generated silylenes Me2Si: with benzyl bromide, 1H‐CIDNP (chemically induced dynamic nuclear polarization) is observed in the radical ion‐recombination product PhCH2‐SiMe2Br formed from singlet states o...

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Veröffentlicht in:	Chemische Berichte 1990-09, Vol.123 (9), p.1927-1928
Hauptverfasser:	Lehnig, Manfred, Reininghaus, Frank
Format:	Artikel
Sprache:	eng
Schlagworte:	CIDNP Insertion reaction Radical reaction Singlet silylenes
Online-Zugang:	Volltext
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Zusammenfassung:	1H‐CIDNP During an Insertion Reaction of Dimethylsilylenes During the reaction of photochemically generated silylenes Me2Si: with benzyl bromide, 1H‐CIDNP (chemically induced dynamic nuclear polarization) is observed in the radical ion‐recombination product PhCH2‐SiMe2Br formed from singlet states of Me2Si:.
ISSN:	0009-2940 1099-0682
DOI:	10.1002/cber.19901230926