Aminolyse von 2,5‐Bis(aryloxy)‐3,3aγ4,4‐trithia‐1,6‐diazapentalenen — ein Zugang zu makrocyclischen Heteropentalenen

Aminolysis of 2,5‐Bis(aryloxy)‐3,3aγ4,4‐trithia‐1,6‐diazapentalenes ‐ an Entry to Macrocyclic Heteropentalenes The N,N′‐bis(3,3aγ4‐trithia‐1,6‐diazapentalenyl)diamines 6, 7 and azacrown ethers 8, incorporating two sulfur‐containing diazapentalenes, have been synthesized from 2,5‐bis(aryloxy)‐3,3aγ4,4‐trithia‐1,6‐diazapentalenes 1 and diamines. The aminolysis of 1 with amines has also been studied providing 2‐monoamino‐ 3 and 2,5‐diaminoheteropentalenes 4. Aminolyse von 2,5‐Bis(aryloxy)‐3,3aλ4,4‐trithia‐1,6‐diazapentalenen — ein Zugang zu makrocyclischen Heteropentalenen Aminolysis of 2,5‐Bis(aryloxy)‐3,3aλ4,4‐trithia‐1,6‐diazapentalenes — an Entry to Macrocyclic Heteropentalenes