Unveiling Oxygen Evolution Reaction on LiCoO2 Cathode: Insights for the Development of High‐Performance Aqueous Lithium‐ion Batteries

Aqueous lithium‐ion batteries (ALIBs) are attracting significant attention as promising candidates for safe and sustainable energy storage systems. This paper delves into the crucial aspects of ALIB technology focusing on the interaction between LiCoO2 (lithium cobalt oxide) cathode material and wat...

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Veröffentlicht in:Batteries & supercaps 2024-02, Vol.7 (2), p.n/a
Hauptverfasser: George, Gibu, Poater, Albert, Solà, Miquel, Posada‐Pérez, Sergio
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Sprache:eng
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Zusammenfassung:Aqueous lithium‐ion batteries (ALIBs) are attracting significant attention as promising candidates for safe and sustainable energy storage systems. This paper delves into the crucial aspects of ALIB technology focusing on the interaction between LiCoO2 (lithium cobalt oxide) cathode material and water electrolytes, with a specific emphasis on the Oxygen Evolution Reaction (OER) process. Fundamental understanding of the electrochemical behavior of LiCoO2 in aqueous electrolytes is crucial for enhancing the performance, safety, and longevity of ALIBs using LiCoO2 as the cathode material. Through a comprehensive periodic density functional analysis of the LiCoO2‐water at the cathode interface, the potential catalytic contributions to the OER mechanism of LiCoO2 are explored. The catalytic properties of LiCoO2 towards OER are investigated considering different steady states of the lowest energy surfaces of LiCoO2 and three different Li concentrations. Our results do not predict the formation of oxygen gas due to the expected large overpotentials, although the exergonic water decomposition to hydroxyl by means the first proton‐electron transfer is predicted at equilibrium potential. This work contributes to the fundamental understanding of LiCoO2 as cathode for aqueous lithium‐ion batteries, reporting the pros and cons of one of the most common cathode materials for traditional non‐aqueous batteries. Lithium cobalt oxide surfaces exhibit a substantial overpotential for the oxygen evolution reaction. While this quality holds promise for efficient energy storage, it degrades water electrolyte, leading to the production of hydroxide. Balancing the catalytic benefits with the electrolyte impact becomes crucial in optimizing the performance of lithium cobalt oxide for sustainable electrochemical applications.
ISSN:2566-6223
2566-6223
DOI:10.1002/batt.202300452