Cover Picture: Between Elemental Match and Mismatch: From K12Ge3.5Sb6 to Salts of (Ge2Sb2)2−, (Ge4Sb12)4−, and (Ge4Sb14)4− (Angew. Chem. Int. Ed. 41/2022)

First explorations of binary Ge/Sb Zintl anions indicated a situation between a “matching” one and one that tends to element segregation owing to a mismatch in atom sizes. Extraction of the ternary solid K12Ge3.5Sb6 allowed access to the so far missing P4‐like anion (Ge2Sb2)2−, as well as to species that show tendencies for spatial separation of Ge and Sb atoms, “incomplete” (Ge4Sb12)4− and “complete” (Ge4Sb14)4−, as confirmed by DFT calculations and described by Stefanie Dehnen et al. in their Research Article (e202207232).