Tungsten-Mediated Activation of a PbII----N bond: A New Route to Tungsten-Lead Triple Bonds

A WPb bond is present in the hydrido plumbylidyne complex trans‐[H(PMe3)4WPb(2,6‐Trip2C6H3)], which is formed by an unprecedented PbN activation reaction of {Pb(2,6‐Trip2C6H3)NMe2}2, the first structurally characterized organolead(II) amide (see picture for molecular structure). Trip=2,4,6‐iPr3C6...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2008-07, Vol.47 (31), p.5799-5802
Hauptverfasser:	Filippou, Alexander C, Weidemann, Nils, Schnakenburg, Gregor
Format:	Artikel
Sprache:	eng
Schlagworte:	amides hydride ligands lead PbN activation tungsten
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Beschreibung
Zusammenfassung:	A WPb bond is present in the hydrido plumbylidyne complex trans‐[H(PMe3)4WPb(2,6‐Trip2C6H3)], which is formed by an unprecedented PbN activation reaction of {Pb(2,6‐Trip2C6H3)NMe2}2, the first structurally characterized organolead(II) amide (see picture for molecular structure). Trip=2,4,6‐iPr3C6H2.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.200801331