Hydroxylation of Benzene to Phenol under Air and Carbon Monoxide Catalyzed by Molybdovanadophosphoric Acid

Hydroxylation of Benzene to Phenol under Air and Carbon Monoxide Catalyzed by Molybdovanadophosphoric Acid

The simpler, the better: Phenol is synthesized by the direct oxidation of benzene under air (15 atm) and CO (10 atm) with molybdovanadophosphoric acid as the catalyst (see scheme). Activated molecular oxygen serves as the oxidant and phenol is produced in 28 % yield. The catalyst can be recovered an...

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Veröffentlicht in:Angewandte Chemie International Edition 2005-04, Vol.44 (17), p.2586-2588
Hauptverfasser: Tani, Masayuki, Sakamoto, Takao, Mita, Shuichi, Sakaguchi, Satoshi, Ishii, Yasutaka
Format: Artikel
Sprache:eng
Schlagworte:
hydrocarbons
hydroxylation
oxidation
oxygen
synthetic methods
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Zusammenfassung:The simpler, the better: Phenol is synthesized by the direct oxidation of benzene under air (15 atm) and CO (10 atm) with molybdovanadophosphoric acid as the catalyst (see scheme). Activated molecular oxygen serves as the oxidant and phenol is produced in 28 % yield. The catalyst can be recovered and reused.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200462769