Five‐Coordinate Sulfur in a Polymeric Copper(I) Thiolate Complex

Five‐Coordinate Sulfur in a Polymeric Copper(I) Thiolate Complex

Strong electron‐deficient bonds with four equivalent copper(I) centers as well as the carbon atom of the organic group are a feature of the thiolate sulfur atoms of the new cage [(CuCl)12(SR)6] (R  CH2CH2NH3; structure on the right, Cl and R omitted). This is part of the polymeric complex [Cu13Cl13...

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Veröffentlicht in:Angewandte Chemie International Edition 1997-02, Vol.36 (3), p.251-253
Hauptverfasser: Parish, Richard V., Salehi, Zahra, Pritchard, Robin G.
Format: Artikel
Sprache:eng
Schlagworte:
cage compounds
clusters
coordination modes
copper
S ligands
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Zusammenfassung:Strong electron‐deficient bonds with four equivalent copper(I) centers as well as the carbon atom of the organic group are a feature of the thiolate sulfur atoms of the new cage [(CuCl)12(SR)6] (R  CH2CH2NH3; structure on the right, Cl and R omitted). This is part of the polymeric complex [Cu13Cl13(SR)6], which is accessible from cysteamine hydrochloride and copper(I) chloride. • = Cu, ○ = S.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199702511