C59N+ and C69N+: Isoelectronic Heteroanalogues of C60 and C70

C59N+ and C69N+: Isoelectronic Heteroanalogues of C60 and C70

Fragmentation reactions in the mass spectrometer were used to generate the first characterized nitrogen heterofullerene ions C59N+ and C69N+ from regioselectively synthesized oligoiminofullerenes. During this process one carbon atom in the fullerene core is removed and replaced with a nitrogen atom....

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Veröffentlicht in:Angewandte Chemie International Edition 1995-11, Vol.34 (20), p.2257-2259
Hauptverfasser: Lamparth, Iris, Nuber, Berthold, Schick, Georg, Skiebe, Andreas, Grösser, Thomas, Hirsch, Andreas
Format: Artikel
Sprache:eng
Schlagworte:
fullerenes
heterofullerenes
mass spectrometry
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Beschreibung
Zusammenfassung:Fragmentation reactions in the mass spectrometer were used to generate the first characterized nitrogen heterofullerene ions C59N+ and C69N+ from regioselectively synthesized oligoiminofullerenes. During this process one carbon atom in the fullerene core is removed and replaced with a nitrogen atom. C59N+ (shown on the right) has almost the same structure as the isoelectronic C60.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199522571