Pd Clusters Containing As and PPh3 Ligands: The Structures of [Pd9As6 (PPh3)8], [Pd2(As2)(PPh3)4], and [Pd20As12 (PPh3)12]

Pd Clusters Containing As and PPh3 Ligands: The Structures of [Pd9As6 (PPh3)8], [Pd2(As2)(PPh3)4], and [Pd20As12 (PPh3)12]

A Pd20 polyhedron all of whose surfaces are bridged by μ5‐As atoms is one distinctive feature of 1, the title compound with the highest Pd content. Compound 1 was obtained upon treatment of [PdCl2(PPh3)2] with As(SiMe3)3. Other products of the reaction were the Pd2 and Pd9 complexes mentioned in the...

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Veröffentlicht in:Angewandte Chemie International Edition 1989-12, Vol.28 (12), p.1665-1667
Hauptverfasser: Fenske, Dieter, Fleischer, Holm, Persau, Claudia
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container_title Angewandte Chemie International Edition
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creator Fenske, Dieter
Fleischer, Holm
Persau, Claudia
description A Pd20 polyhedron all of whose surfaces are bridged by μ5‐As atoms is one distinctive feature of 1, the title compound with the highest Pd content. Compound 1 was obtained upon treatment of [PdCl2(PPh3)2] with As(SiMe3)3. Other products of the reaction were the Pd2 and Pd9 complexes mentioned in the title as well, whereby the Pd9 complex also results from the reaction of [Pd3S2Cl2(PPh3)4] with As(SiMe3)3.
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title Pd Clusters Containing As and PPh3 Ligands: The Structures of [Pd9As6 (PPh3)8], [Pd2(As2)(PPh3)4], and [Pd20As12 (PPh3)12]
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