Pd Clusters Containing As and PPh3 Ligands: The Structures of [Pd9As6 (PPh3)8], [Pd2(As2)(PPh3)4], and [Pd20As12 (PPh3)12]
A Pd20 polyhedron all of whose surfaces are bridged by μ5‐As atoms is one distinctive feature of 1, the title compound with the highest Pd content. Compound 1 was obtained upon treatment of [PdCl2(PPh3)2] with As(SiMe3)3. Other products of the reaction were the Pd2 and Pd9 complexes mentioned in the...
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| Veröffentlicht in: | Angewandte Chemie International Edition 1989-12, Vol.28 (12), p.1665-1667 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A Pd20 polyhedron all of whose surfaces are bridged by μ5‐As atoms is one distinctive feature of 1, the title compound with the highest Pd content. Compound 1 was obtained upon treatment of [PdCl2(PPh3)2] with As(SiMe3)3. Other products of the reaction were the Pd2 and Pd9 complexes mentioned in the title as well, whereby the Pd9 complex also results from the reaction of [Pd3S2Cl2(PPh3)4] with As(SiMe3)3. |
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| ISSN: | 0570-0833 1521-3773 |
| DOI: | 10.1002/anie.198916651 |