[Et4N]6[Na14Mo24P17O97(OH)31]·xH2O: A Hollow Cluster Filled with 12 Na⊕ Ions and a H3PO4 Molecule
The hydrothermal reaction of Na2MoO4, Mo, H3PO4, Et4NOH, and H2O yields the title complex, the structure of which is characterized by tetramers of [Mo6P4O24(OH)7]5⊖ units 1 (Mo = hatched, P = dotted, O = empty circle). The complex structure of the reduced molybdenum phosphate can be rationalized by...
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| Veröffentlicht in: | Angewandte Chemie International Edition 1989-06, Vol.28 (6), p.743-746 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The hydrothermal reaction of Na2MoO4, Mo, H3PO4, Et4NOH, and H2O yields the title complex, the structure of which is characterized by tetramers of [Mo6P4O24(OH)7]5⊖ units 1 (Mo = hatched, P = dotted, O = empty circle). The complex structure of the reduced molybdenum phosphate can be rationalized by the differing hydrophilicities of MoO6 and PO4 structural units. |
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| ISSN: | 0570-0833 1521-3773 |
| DOI: | 10.1002/anie.198907431 |