17- to 19-Electron Pentamethylcyclopentadienyl Iron Dithiocarbamate Complexes. Formation of a CpFeIV Complex
The “electron‐reservoir” properties of ⊖SC(S)NMe2 are demonstrated by the facile interconversion of the 17‐electron complexes 1⊕ and the 18‐electron complexes 1(L = CO, MeCN, Me2CO, CH2Cl2) as well as by the reaction of complex 1⊕, L = CO, with NaSC(S)NMe2·2H2O to give the symmetrical complex 1, L =...
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| Veröffentlicht in: | Angewandte Chemie International Edition 1989-04, Vol.28 (4), p.460-461 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The “electron‐reservoir” properties of ⊖SC(S)NMe2 are demonstrated by the facile interconversion of the 17‐electron complexes 1⊕ and the 18‐electron complexes 1(L = CO, MeCN, Me2CO, CH2Cl2) as well as by the reaction of complex 1⊕, L = CO, with NaSC(S)NMe2·2H2O to give the symmetrical complex 1, L = SC(S)NMe2, with reduction of water. |
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| ISSN: | 0570-0833 1521-3773 |
| DOI: | 10.1002/anie.198904601 |