Cyclo[d.e.d.e.e.d.e.d.e.e.]decakisbenzene, a New Cycloarene

Cyclo[d.e.d.e.e.d.e.d.e.e.]decakisbenzene, a New Cycloarene

The new parent hydrocarbon 1 is the second cycloarene (after kekulene) that consists of twelve symmetrically arranged benzene rings. 1 forms yellow crystals and was prepared by photocyclization of a partially hydrogenated benzophenanthrenophanediene. Compound 1 contains 40 π electrons, but can be fo...

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Veröffentlicht in:Angewandte Chemie International Edition 1986-08, Vol.25 (8), p.742-744
Hauptverfasser: Funhoff, Dirk J. H., Staab, Heinz A.
Format: Artikel
Sprache:eng
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Zusammenfassung:The new parent hydrocarbon 1 is the second cycloarene (after kekulene) that consists of twelve symmetrically arranged benzene rings. 1 forms yellow crystals and was prepared by photocyclization of a partially hydrogenated benzophenanthrenophanediene. Compound 1 contains 40 π electrons, but can be formulated with an inner and an outer [4n + 2] π‐electron perimeter.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.198607421