Selective Synthesis of Carbonyl Olefinating or Alkylating Reagents from MoCl5 and MeLi by Changing the Solvent or the Rate of Addition of MeLi
The simple change from rapid to slow admixture of the educts is decisive in determining whether carbonyl olefinating reagents (1, 2) + CH4 or carbonyl alkylating reagents (3, 4) + ethane are formed from MoCl5 and MeLi in tetrahydrofuran.
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| Veröffentlicht in: | Angewandte Chemie International Edition 1984-07, Vol.23 (7), p.532-533 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The simple change from rapid to slow admixture of the educts is decisive in determining whether carbonyl olefinating reagents (1, 2) + CH4 or carbonyl alkylating reagents (3, 4) + ethane are formed from MoCl5 and MeLi in tetrahydrofuran. |
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| ISSN: | 0570-0833 1521-3773 |
| DOI: | 10.1002/anie.198405321 |