A conducting thallium salt of 2,5-dimethyl-N, N′-dicyanoquinone-diimine, [2,5-DMe-DCNQI]2Tl: Comparison with other related radical anion salts

A conducting thallium salt of 2,5-dimethyl-N, N′-dicyanoquinone-diimine, [2,5-DMe-DCNQI]2Tl: Comparison with other related radical anion salts

A radical anion salt based on thallium (see figure, where M = Tl) has been prepared. It is found to be the only such conducting compound, except the copper analogue, which shows a positive NMR knight shift indicating an electronic interaction between the central atom and the ligand.

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Veröffentlicht in:Advanced materials (Weinheim) 1990-08, Vol.2 (8), p.361-363
Hauptverfasser: Hünig, Siegfried, Meixner, Hubert, Metzenthin, Tobias, Langohr, Uwe, von Schütz, Jost Ulrich, Wolf, Hans-Christopf, Tillmanns, Ekkehart
Format: Artikel
Sprache:eng
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Zusammenfassung:A radical anion salt based on thallium (see figure, where M = Tl) has been prepared. It is found to be the only such conducting compound, except the copper analogue, which shows a positive NMR knight shift indicating an electronic interaction between the central atom and the ligand.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.19900020805