REDOX CHEMISTRY OF RU(OEP)(CH3)2 - ISOLATION OF THE BRIDGING METHYLENE COMPLEX RU(OEP-N-MU-CH2-)(CH3)

REDOX CHEMISTRY OF RU(OEP)(CH3)2 - ISOLATION OF THE BRIDGING METHYLENE COMPLEX RU(OEP-N-MU-CH2-)(CH3)

The first example of a porphyrin complex with a bridging CH2, Ru(OEP-N-mu-CH2-)(CH3)+, has been isolated as part of a study of the redox-induced reactions of Ru(OEP)(CH3)2 (OEP = octaethylporphyrin dianion). The methylene-bridged complex is formed by H. abstraction from the Ru(OEP-N-CH3)(CH3)+ compl...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Inorganic chemistry 1992-04, Vol.31 (9), p.1545-1547
Hauptverfasser: SEYLER, JW, SAFFORD, LK, FANWICK, PE, LEIDNER, CR
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry, Inorganic & Nuclear
Electrochemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
Physical Sciences
Science & Technology
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The first example of a porphyrin complex with a bridging CH2, Ru(OEP-N-mu-CH2-)(CH3)+, has been isolated as part of a study of the redox-induced reactions of Ru(OEP)(CH3)2 (OEP = octaethylporphyrin dianion). The methylene-bridged complex is formed by H. abstraction from the Ru(OEP-N-CH3)(CH3)+ complex.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic00035a001