Relocation and reinforcement of the adhesive/composite interface with spontaneous amine-peroxide interfacial polymerization

Hypothesis: “autonomous interfacial redox polymerization prior to composite photopolymerization will increase the bonding between adhesive and composite by reducing interfacial stress with homogenized polymer structures.” [Display omitted] •Amine-peroxide can be segregated between photocured adhesive and resin-composites.•Resin photocuring rate and conversion is enhanced with included amine or peroxide.•Interfacial diffusion and base layer redox cure of the composite begin in