Bismuth(III) Iodide Complexes with 1-Ethyl-4-Dimethylaminopyridinium: Structure, Thermal Stability, and Optical Properties

Bismuth(III) Iodide Complexes with 1-Ethyl-4-Dimethylaminopyridinium: Structure, Thermal Stability, and Optical Properties

Polynuclear bismuth(III) iodide complexes with 1-ethyl-4-dimethylaminopyridinium (1-EtDMAP) 4 [Bi 8 I 28 ] ( 1 ) and (1-EtDMAP)BiI 4 ( 2 ) have been obtained by the reactions of bismuth(III) iodide with an organic iodide salt cations in organic solvents and characterized by X-ray diffraction. The op...

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Veröffentlicht in:Russian journal of inorganic chemistry 2021-10, Vol.66 (10), p.1482-1487
Hauptverfasser: Usol’tsev, A. N., Shentseva, I. A., Shayapov, V. R., Plyusnin, P. E., Korol’kov, I. V., Sokolov, M. N., Adonin, S. A.
Format: Artikel
Sprache:eng
Schlagworte:
Bismuth
Chemistry
Chemistry and Materials Science
Chemistry, Inorganic & Nuclear
Coordination Compounds
Inorganic Chemistry
Optical properties
Physical Sciences
Science & Technology
Structural stability
Thermal stability
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Zusammenfassung:Polynuclear bismuth(III) iodide complexes with 1-ethyl-4-dimethylaminopyridinium (1-EtDMAP) 4 [Bi 8 I 28 ] ( 1 ) and (1-EtDMAP)BiI 4 ( 2 ) have been obtained by the reactions of bismuth(III) iodide with an organic iodide salt cations in organic solvents and characterized by X-ray diffraction. The optical properties and thermal stability of the obtained compounds have been studied.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023621100193