Study of Charge Transfer Mechanism and Dielectric Relaxation of CsCuCl3 Perovskite Nanoparticles

•The nyquist diagrams demonstrate the contribution of the grain and grain boundary in the relaxation mechanism inside CsCuCl3. The maxwell–wagner model was used to draw the equivalent circuit.•The drastic enhancement of relative permittivity in the CsCuCl3 compound was explained using the double maxwell-wagner layer proposed by koop's theory.•The asymmetric electric modulus curve obtained from the measurement was evaluated with the KWW equation. It was found that, with the elevation in temperature, the non-Debye nature of the imaginary part of the electric modulus decreases.•Activation energy was determined from different formalism and the same value proposes that the same type of charge carriers involve for conduction as well as relaxation process.•The AC conductivity study suggested that small polaron hopping which was due to the high mobility of Cs+ was the most possible charge transport mechanism in CsCuCl3. Non-toxic inorganic metal halide perovskites have commercially established dominance over all the other optoelectronic devices. In this paper, a non-toxic CsCuCl3 metal halide is successfully synthesized through the slow evaporation solution growth technique. The hexagonal phase of the material is checked using the X-ray diffraction measurement. The morphological study indicates the spherical shape of nanoparticles with about 20 nm size. CsCuCl3 demonstrates a semiconducting property with a direct band gap value of approximately 2.18 eV. Over the 10−1–107 Hz frequency range, the dielectric constant, the loss factor, the electric modulus and also the electrical conductivity of CsCuCl3 show strong temperature dependence. The Nyquist plot confirms the various contributions of grains and grain boundaries to the total impedance. In the high-frequency region, the dielectric constant tends to increase with temperature. The modified Cole–Cole plot asserts that while the relaxation time decreases with the rise in temperature, the space charge and free charge conductivity increase the moment the temperature climbs. In accordance with the modified Kohlrausch-Williams-Watts (KWW) equation, an asymmetrical nature corresponding to the non-Debye type of the perovskite is noticed in the electric modulus spectra at different temperatures. Moreover, the imaginary part of the electric modulus spectra is found to shift from the non-Debye toward the Debye type with the increase in temperature despite not getting the exact Debye response and emerging as a semi-conductor